Ballardini R, Balzani V, Credi A, Gandolfi M T, Venturi M
Istituto FRAE-CNR, via Gobetti 101, 40129 Bologna, Italy.
Acc Chem Res. 2001 Jun;34(6):445-55. doi: 10.1021/ar000170g.
The concept of machine can be extended to the molecular level by designing and synthesizing (supra)molecular species capable of performing mechanical movements. The energy needed to make a machine work can be supplied as chemical energy, electrical energy, or light. When a chemical "fuel" is used, waste products are formed, whereas this is not the case when suitable photochemical or electrochemical energy inputs are employed. A number of elementary functions performed by molecular-level machines are illustrated, and more complex ones are foreseen.
通过设计和合成能够执行机械运动的(超)分子物种,机器的概念可以扩展到分子水平。使机器运转所需的能量可以作为化学能、电能或光能提供。当使用化学“燃料”时,会形成废物,而当采用合适的光化学或电化学能量输入时则不会出现这种情况。文中展示了分子水平机器执行的一些基本功能,并预见了更复杂的功能。