Mulligan C N, Yong R N, Gibbs B F
Department of Building, Civil and Environmental Engineering, Concordia University, 1455 de Maisonneuve Blvd. W., Montreal, Quebec, Canada H3G 1M8.
J Hazard Mater. 2001 Jul 30;85(1-2):145-63. doi: 10.1016/s0304-3894(01)00226-6.
Sediments dewatering is frequently necessary after dredging to remediate and treat contaminants. Methods include draining of the water in lagoons with or without coagulants and flocculants, or using presses or centrifuges. Treatment methods are similar to those used for soil and include pretreatment, physical separation, thermal processes, biological decontamination, stabilization/solidification and washing. However, compared to soil treatment, few remediation techniques have been commercially used for sediments. In this paper, a review of the methods that have been used and an evaluation of developed and developing technologies is made. Sequential extraction technique can be a useful tool for determining metal speciation before and after washing. Solidification/stabilization techniques are successful but significant monitoring is required, since the solidification process can be reversible. In addition, the presence of organics can reduce treatment efficiency. Vitrification is applicable for sediments but expensive. Only if a useful glass product can be sold will this process be economically viable. Thermal processes are only applicable for removal of volatile metals, such as mercury and costs are high. Biological processes are under development and have the potential to be low cost. Since few low cost metal treatment processes for sediments are available, there exists significant demand for further development. Pretreatment may be one of the methods that can reduce costs by reducing the volumes of sediments that need to be treated.
疏浚后,沉积物脱水通常是修复和处理污染物所必需的。方法包括在有或没有混凝剂和絮凝剂的情况下排放泻湖中的水,或使用压滤机或离心机。处理方法与土壤处理方法类似,包括预处理、物理分离、热法、生物净化、稳定化/固化和清洗。然而,与土壤处理相比,很少有修复技术在沉积物处理中得到商业应用。本文对已使用的方法进行了综述,并对已开发和正在开发的技术进行了评估。顺序提取技术可以作为一种有用的工具,用于确定洗涤前后金属的形态。固化/稳定化技术是成功的,但需要进行大量监测,因为固化过程可能是可逆的。此外,有机物的存在会降低处理效率。玻璃化适用于沉积物,但成本高昂。只有当有用的玻璃产品能够销售时,这个过程才在经济上可行。热法仅适用于去除挥发性金属,如汞,且成本很高。生物法正在开发中,有可能成本较低。由于沉积物低成本金属处理工艺很少,因此对进一步开发有很大需求。预处理可能是通过减少需要处理的沉积物量来降低成本的方法之一。