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用于处理含非离子型合成表面活性剂废水的BAC工艺。

The BAC-process for treatment of waste water containing non-ionogenic synthetic surfactants.

作者信息

Sirotkin A S, Ippolitov K G

机构信息

Department of Chemical Cybernetic, The State Technological University, Kazan, Russia.

出版信息

Water Res. 2001 Sep;35(13):3265-71. doi: 10.1016/s0043-1354(01)00029-x.

Abstract

In this paper experimental results on the biological-activated carbon (BAC)-process for biological degradation and adsorption of non-ionogenic surfactants (NISS) in the waste water treatment are discussed. It is shown that the mechanism of the BAC-process is not the simple addition but the synergetic combination of biodegradation and carbon adsorption. The major aspects of such synergism are the biological regeneration (bioregeneration) of the adsorbent and the reduction of the toxic effect of waste water contaminants on microorganisms. It is shown that the basis of the bioregeneration process is the desorption of substances previously adsorbed on the activated carbon. The desorption from micropores takes place because of the reverse concentration gradient, due to the microbial degradation of waste water contaminants in the liquid phase. The desorption from mesopores is also supported by the activity of microorganisms exoenzymes. Thus, the process of bioregeneration is featured by two non-contradictory hypotheses.

摘要

本文讨论了生物活性炭(BAC)工艺在废水处理中对非离子表面活性剂(NISS)进行生物降解和吸附的实验结果。结果表明,BAC工艺的机理并非简单的相加,而是生物降解与碳吸附的协同组合。这种协同作用的主要方面是吸附剂的生物再生以及降低废水污染物对微生物的毒性作用。结果表明,生物再生过程的基础是先前吸附在活性炭上的物质的解吸。由于液相中废水污染物的微生物降解,导致浓度梯度反转,从而使微孔中的物质发生解吸。中孔的解吸也受到微生物外酶活性的支持。因此,生物再生过程具有两个互不矛盾的假设。

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