Covaci A, Hura C, Schepens P
Toxicological Center, University of Antwerp, Wilrijk, Belgium.
Sci Total Environ. 2001 Dec 3;280(1-3):143-52. doi: 10.1016/s0048-9697(01)00820-8.
Selected persistent organochlorine pollutants, including PCBs, DDT and its metabolites (DDTs) and hexachlorocyclohexane isomers (HCHs) were determined in soil, animal fat and human serum samples from Romania. All methods were rigorously tested and adequate quality control was ensured. Soil samples from lassy County showed a lower contamination with organochlorines than samples from other Romanian regions. While DDTs concentrations in soil were significantly higher at rural sites, only few samples (three out of 47) exceeded the official Romanian norms for DDTs. PCBs concentrations were low in rural sites (< 8 ng/g soil), but rather high (up to 134 ng/g soil) in urban soils collected mostly from parks (Bucharest, Arad, Baia Mare, Pitesti and Ploicsti). Animal fat samples from lassy showed high concentrations of organochlorine pesticides (HCHs concentrations up to 12370 ng/g fat), but similar PCB concentrations when compared with Arad samples. Two samples (from 24) exceeded the EU norms (1000 ng/g fat) for HCHs and DDTs in animal fat. Organochlorines were found in higher concentrations in some samples of human serum from Timisoara due to a broader age range. Samples of human serum from lassy mothers showed higher HCHs and DDTs concentrations than samples from a similar group from Antwerp, Belgium. HCB and PCBs were higher in Antwerp cohort. Romanian samples showed a higher ratio DDT/sigmaDDTs, but similar ratios PCB 153/sigmaPCBs.
在罗马尼亚采集的土壤、动物脂肪和人体血清样本中,测定了包括多氯联苯(PCBs)、滴滴涕(DDT)及其代谢物(DDTs)和六氯环己烷异构体(HCHs)在内的选定持久性有机氯污染物。所有方法均经过严格测试,并确保了充分的质量控制。拉西县的土壤样本显示,有机氯污染程度低于罗马尼亚其他地区的样本。虽然农村地区土壤中的滴滴涕浓度显著较高,但只有少数样本(47个样本中的3个)超过了罗马尼亚官方规定的滴滴涕标准。农村地区的多氯联苯浓度较低(<8纳克/克土壤),但在主要从公园采集的城市土壤中(布加勒斯特、阿拉德、巴亚马雷、皮特什蒂和普洛耶什蒂)相当高(高达134纳克/克土壤)。拉西的动物脂肪样本显示有机氯农药浓度很高(六氯环己烷浓度高达12370纳克/克脂肪),但与阿拉德样本相比,多氯联苯浓度相似。24个动物脂肪样本中有2个超过了欧盟规定的六氯环己烷和滴滴涕标准(1000纳克/克脂肪)。由于年龄范围更广,蒂米什瓦拉的一些人体血清样本中发现有机氯浓度更高。拉西母亲的人体血清样本显示,六氯环己烷和滴滴涕浓度高于比利时安特卫普类似群体的样本。安特卫普队列中的六氯苯和多氯联苯含量较高。罗马尼亚样本显示滴滴涕/总滴滴涕的比例较高,但多氯联苯153/总多氯联苯的比例相似。