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碳质球粒陨石的有机成分。

Organic constituents of carbonaceous chondrites.

作者信息

Briggs M H, Mamikunian G

机构信息

Jet Propulsion Laboratory, California Institute of Technology, Pasadena, USA.

出版信息

Life Sci Space Res. 1964;2:57-85.

Abstract

From a brief discussion of forms of meteorite carbon it is concluded that almost all the carbon in the carbonaceous chondrites is present as organic matter. Attempts to extract and identify this organic matter are then reviewed. It is shown that only 25 per cent has been extracted and only about 5 per cent chemically characterized. Of this 5 per cent, most is a complex mixture of hydroxylated aromatic acids together with various hydrocarbons of the paraffin, naphthene and aromatic series. Small amounts of amino acids, sugars and fatty acids also are present. The possible chemical nature of the major fraction is discussed. It is suggested to be a mixture of high-molecular weight aromatic and hydrocarbon polymers. Possible sources of contamination of the meteorites are described and evidence indicating a general lack of organic contaminants is presented. It is concluded, that most of the organic constituents are indigenous to the meteorites and are extra terrestrial in origin. Synthetic processes for the compounds are mentioned and it is concluded that the organic material is probably of abiogenic origin. A brief review on studies of "organized elements" contained within the meteorites is presented. Difficulties of identification are discussed and photographs of some microstructures of several carbonaceous chondrites are presented. No final conclusion about the nature of these objects is possible, but some appear to be various indigenous organic and mineral structures, while others are terrestrial contaminants.

摘要

通过对陨石碳形式的简要讨论得出结论,碳质球粒陨石中的几乎所有碳都以有机物形式存在。接着回顾了提取和鉴定这种有机物的尝试。结果表明,仅25%的有机物被提取出来,且只有约5%得到了化学表征。在这5%中,大部分是羟基化芳香酸与各种链烷、环烷和芳香族系列烃类的复杂混合物。还存在少量氨基酸、糖和脂肪酸。讨论了主要部分可能的化学性质。认为它是高分子量芳香族和烃类聚合物的混合物。描述了陨石可能的污染来源,并给出了表明普遍缺乏有机污染物的证据。得出的结论是,大多数有机成分是陨石固有的,且起源于地球之外。提到了这些化合物的合成过程,并得出结论,有机物质可能起源于非生物。对陨石中“有组织元素”的研究进行了简要回顾。讨论了鉴定的困难,并给出了几种碳质球粒陨石一些微观结构的照片。关于这些物体的性质无法得出最终结论,但有些似乎是各种固有的有机和矿物结构,而其他的则是地球污染物。

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