超分子聚集体中的手性诱导：具有四重螺旋几何结构的武装环糊精 - 钠离子络合物之间的手性识别
Chirality induction in supramolecular aggregate: chiral recognition between armed cyclen-Na+ complexes having quadruplicated helical geometry.
作者信息
Nishimura Tomoko, Shinoda Satoshi, Tsukube Hiroshi
机构信息
Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan.
出版信息
Chirality. 2002 Jul;14(7):555-7. doi: 10.1002/chir.10084.
PMID:12112327
Abstract
A water-soluble self-aggregate of octadentate Na+ complex with chiral cholesterol-armed cyclen provides unique microenvironments for chirality induction of guest cyclen-Na+ complex via supramolecular interaction.
摘要
一种由八齿Na⁺配合物与手性胆固醇修饰的环烯胺形成的水溶性自聚集体，通过超分子相互作用为客体环烯胺-Na⁺配合物的手性诱导提供了独特的微环境。
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