水热条件下菲咯啉的脱氢偶联反应：一种由4,8,10-网层构建的新型层状钒酸盐配合物[(2,2'-联苯)Co]V3O8.5的晶体结构
Dehydrogenative coupling of phenanthroline under hydrothermal conditions: crystal structure of a novel layered vanadate complex constructed of 4,8,10-net sheets: [(2,2'-biphen)Co]V3O8.5.
作者信息
Liu C M, Gao S, Kou H Z
机构信息
State Key Laboratory of Rare Earth Materials Chemistry and Applications & PKU-HKU Joint Laboratory on Rare Earth Materials and Bioinorganic Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China.
出版信息
Chem Commun (Camb). 2001 Sep 7(17):1670-1. doi: 10.1039/b103304m.
DOI:10.1039/b103304m
PMID:12240436
Abstract
2,2'-Biphenanthroline (2,2'-biphen) formed from 1,10-phenanthroline when a new two-dimensional layered vanadium oxide metal coordination complex, [(2,2'-biphen)Co]V3O8.5, which contains novel 4,8,10-net sheets, was hydrothermally synthesized.
摘要
当水热合成一种新型二维层状钒氧化物金属配位络合物[(2,2'-联菲罗啉)钴]V3O8.5时，1,10-菲罗啉会形成2,2'-联菲罗啉，该络合物包含新型的4,8,10-网层。
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