Syed Sabir, Sharma Lalit Mohan, Mohammad A, Syed Akheel Ahmed
Department of Chemistry, N.A.S. College, Meerut-25001, India.
Ann Chim. 2002 Nov-Dec;92(11-12):1143-50.
Gold recovery from spent materials has been performed on modified cation-exchange resin. The modified resin was prepared by sorption of Rhodamine-B on Dowex-50-X8 (Na+) resin at pH 2.0. Distribution coefficients of gold ion have been determined with 15% (w/v) potassium chloride in different concentrations of hydrochloric acid. On the basis of Kd values quantitative separation of gold from secondary sources has been achieved. Gold(III) has been selectively separated from gold containing spent materials by column chromatography using modified ionexchange resin and the recovery was more than 92% compared to conventional cyanidation process. The results of the proposed method are suggestive of its applicability to other gold containing secondary sources.
已在改性阳离子交换树脂上从废旧材料中回收金。改性树脂是通过在pH 2.0条件下将罗丹明B吸附到Dowex - 50 - X8(Na +)树脂上制备的。用15%(w/v)氯化钾在不同浓度的盐酸中测定了金离子的分配系数。基于分配系数值,已实现从二次资源中定量分离金。使用改性离子交换树脂通过柱色谱法从含金废旧材料中选择性分离出金(III),与传统氰化法相比,回收率超过92%。所提出方法的结果表明其适用于其他含金二次资源。