Dioxygen activation by a dinuclear nickel thiolate complex: structural characterization of the ligand oxidized product.
作者信息
Harrop Todd C, Olmstead Marilyn M, Mascharak Pradip K
机构信息
Department of Chemistry and Biochemistry, University of California, Santa Cruz, CA 95064, USA.
出版信息
Chem Commun (Camb). 2003 Feb 7(3):410-1. doi: 10.1039/b211395n.
DOI:10.1039/b211395n
PMID:12613637
Abstract
A (mu-SR)2-nickel(II) dimer derived from a ligand with carboxamido nitrogen and thiolato sulfur donors reacts with O2 to afford an oxidized product in which phenyl groups of the ligand frames are oxidized to nickel-bound phenolates.
摘要
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