Influence of optical thickness and hot electrons on Rydberg spectra of Ne-like and F-like copper ions.

Spectra in the 7.10 to 8.60 A range from highly charged copper ions are observed from three different laser-produced plasmas (LPPs). The LPPs are formed by a 15-ns Nd:glass laser pulse (type I: E(pulse)=1-8 J, lambda=1.064 microm), a 1-ps Nd:glass laser pulse (type II: E(pulse)=1 J, lambda=1.055 microm), and a 60-fs Ti:sapphire laser pulse (type III: E(pulse)=800 mJ, lambda=790 nm). The spectra of high-n (n<or=14) transitions in highly charged copper ions, Cu19+ to Cu21+, are recorded with a high energy resolution (lambda/deltalambda=3000-8000) spectrometer using a spherically bent mica or quartz crystal. Collisional-radiative models are computed for the emission from each plasma. The sensitivity of the model spectra to opacity effects and to populations of superthermal electrons is studied. For the type I LPPs, opacity effects, treated with escape factors, are necessary to get the correct relative intensities of high-n (n=5, 6) Ne-like Cu19+ emission features. In the case of the type II LPPs, the contrast between the laser prepulse and the main pulse has been varied from low, I(main)/I(pp)=7 x 10(4), to high, I(main)/I(pp)=3.8 x 10(7). For plasmas from low contrast shots, we find good agreement between the observed spectra and optically thin simulations with bulk electron temperatures T(bulk)=0.4 keV and a small population of superthermal electrons (T(hot)=5.0 keV) that is f(hot)<or=10(-5) of the bulk electron population. For high-contrast type II LPPs, we find higher densities and a combination of f(hot) approximately 10(-5) and escape factors best describes the data. For the type III 60-fs LPPs, a population of superthermal electrons (T(hot) approximately 5 keV) that is approximately 5 x 10(-5) of the bulk electron population (T(bulk) approximately 0.2 keV) is required to reproduce the observed spectra. The effect of both escape factors and hot electrons in the CR models is to increase the ionization balance and dramatically increase the number of strong lines for each ion considered. We have studied both opacity effects and hot-electron influence on high-n transitions of highly charged Ne-, F-, and O-like ions.