Peng Rong-fei, He Jia-yao, Zhang Zhan-xia
Department of Chemistry, Zhongshan University, Guangzhou 510275, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2002 Feb;22(1):71-4.
The performances of a self-constructed visible AOTF spectrophotometer are presented. The wavelength calibration of AOTF1 and AOTF2 are performed with a didymium glass using a fourth-order polynomial curve fitting method. The absolute error of the peak position is usually less than 0.7 nm. Compared with the commercial UV1100 spectrophotometer, the scanning speed of the AOTF spectrophotometer is much more faster, but the resolution depends on the quality of AOTF. The absorption spectra and the calibration curves of copper sulfate and alizarin red obtained with AOTF1(Institute for Silicate, Shanghai China) and AOTF2 (Brimrose U.S.A) respectively are presented. Their corresponding correlation coefficients of the calibration curves are 0.9991 and 0.9990 respectively. Preliminary results show that the self-constructed AOTF spectrophotometer is feasible.
介绍了自行搭建的可见声光可调谐滤光片(AOTF)分光光度计的性能。使用钕玻璃通过四阶多项式曲线拟合方法对AOTF1和AOTF2进行波长校准。峰值位置的绝对误差通常小于0.7nm。与商用UV1100分光光度计相比,AOTF分光光度计的扫描速度快得多,但分辨率取决于AOTF的质量。分别给出了用AOTF1(中国上海硅酸盐研究所)和AOTF2(美国Brimrose公司)获得的硫酸铜和茜素红的吸收光谱及校准曲线。校准曲线的相应相关系数分别为0.9991和0.9990。初步结果表明自行搭建的AOTF分光光度计是可行的。