Giordani Silvia, Raymo Françisco M
Center for Supramolecular Science, Department of Chemistry, University of Miami, 1301 Memorial Drive, Coral Gables, Florida 33146-0431, USA.
Org Lett. 2003 Oct 2;5(20):3559-62. doi: 10.1021/ol035237p.
[structure: see text] Chemical and optical stimulations control the interconversion of a three-state molecular switch trapped inside a silica monolith. The resulting absorbance changes in the visible region can be exploited to reproduce a sequential logic operator with one optical input and one optical output. This strategy to transfer operating principles for digital processing from bulk solutions to rigid materials can lead to the development of chemical logic gates based on functional solid components.
[结构:见正文] 化学和光刺激控制着被困在硅胶块内部的三态分子开关的相互转换。由此产生的可见光区域吸光度变化可用于重现一个具有一个光输入和一个光输出的顺序逻辑运算符。这种将数字处理操作原理从本体溶液转移到刚性材料的策略可推动基于功能性固体组件的化学逻辑门的发展。