Marenduzzo D, Orlandini E, Yeomans J M
Department of Physics, Theoretical Physics, 1 Keble Road, Oxford OX1 3NP, England.
J Chem Phys. 2004 Jul 1;121(1):582-91. doi: 10.1063/1.1757441.
We study shear flow in liquid crystal cells with elastic deformations using a lattice Boltzmann scheme that solves the full, three-dimensional Beris-Edwards equations of hydrodynamics. We consider first twisted and hybrid aligned nematic cells, in which the deformation is imposed by conflicting anchoring at the boundaries. We find that backflow renders the velocity profile non Newtonian, and that the director profile divides into two regions characterized by different director orientations. We next consider a cholesteric liquid crystal, in which a twist deformation is naturally present. We confirm the presence of secondary flow for small shear rates, and are able to follow the dynamical pathway of shear-induced unwinding, for higher shear rates. Finally, we analyze how the coupling between shear and elastic deformation can affect shear banding in an initially isotropic phase. We find that for a nematic liquid crystal, elastic distortions may cause an asymmetry in the dynamics of band formation, whereas for a cholesteric, shear can induce twist in an initially isotropic sample.
我们使用一种格子玻尔兹曼方法研究具有弹性变形的液晶盒中的剪切流,该方法求解完整的三维流体动力学贝里斯 - 爱德华兹方程。我们首先考虑扭曲向列相和混合排列向列相液晶盒,其中变形是由边界处相互冲突的锚定条件施加的。我们发现回流使速度分布呈现非牛顿特性,并且指向矢分布分为两个以不同指向矢方向为特征的区域。接下来我们考虑胆甾相液晶,其中自然存在扭曲变形。我们证实了在小剪切速率下二次流的存在,并且对于较高剪切速率,能够追踪剪切诱导解缠的动力学路径。最后,我们分析剪切与弹性变形之间的耦合如何影响初始各向同性相中的剪切带化。我们发现对于向列相液晶,弹性畸变可能导致带形成动力学中的不对称性,而对于胆甾相,剪切可以在初始各向同性样品中诱导扭曲。