双（二叔丁基膦甲基）苯钯配合物催化末端烯烃和内烯烃高选择性地形成线性酯。
Highly selective formation of linear esters from terminal and internal alkenes catalysed by palladium complexes of bis-(di-tert-butylphosphinomethyl)benzene.
作者信息
Jimenez Rodriguez Cristina, Foster Douglas F, Eastham Graham R, Cole-Hamilton David J
机构信息
School of Chemistry, University of St. Andrews, St. Andrews, Fife, Scotland KY16 9ST, UK.
出版信息
Chem Commun (Camb). 2004 Aug 7(15):1720-1. doi: 10.1039/b404783d. Epub 2004 Jun 24.
DOI:10.1039/b404783d
PMID:15278154
Abstract
The methoxycarbonylation of terminal or internal alkenes catalysed by palladium complexes of bis-(di-tert-butylphosphinomethyl)benzene under mild conditions leads to linear esters in 99% selectivity via a hydride mechanism.
摘要
在温和条件下，双（二叔丁基膦甲基）苯钯配合物催化末端或内烯烃的甲氧基羰基化反应，通过氢化物机理以99%的选择性生成直链酯。
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