Lin Yan-Jun, Li Dian-Qing, Wang Ge, Huang Lei, Duan Xue
Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry of Education, Beijing University of Chemical Technology, Beijing, 100029, People's Republic of China.
J Mater Sci Mater Med. 2005 Jan;16(1):53-6. doi: 10.1007/s10856-005-6446-0.
After being impregnated in the solution containing Mg(NO3)2 x 6H2O, gamma-Al2O3 was dried and calcined at 500 degrees C which results in the production of a bactericide, highly dispersed MgO loaded on the surface of gamma-Al2O3. The threshold value of the monolayer dispersion of MgO on gamma-Al2O3 is 14.97%, and MgO crystal formed when the load amount beyond this value. The samples with different load amount were characterized by X-ray Diffraction (XRD), Low-temperature N2 adsorption-desorption, Inductively Coupled Plasma (ICP) and High Resolution Scan Electronic Microscope (SEM). The results showed that these MgO microcrystals are highly dispersed and have regular size in the range of 4 to 10.8 nm. The specific surface, pore volume and pore size of the sample decreases with the increase of load amount. It is demonstrated that gamma-Al2O3 with highly dispersed MgO on the surface is efficient bactericide, and the one with 20% load amount of MgO can kill more than 99% bacteria and spore cells.
将γ-Al₂O₃浸渍在含有Mg(NO₃)₂·6H₂O的溶液中后,进行干燥并在500℃下煅烧,从而制得一种杀菌剂,即高度分散在γ-Al₂O₃表面的MgO。MgO在γ-Al₂O₃上的单层分散阈值为14.97%,当负载量超过此值时会形成MgO晶体。采用X射线衍射(XRD)、低温N₂吸附-脱附、电感耦合等离子体(ICP)和高分辨率扫描电子显微镜(SEM)对不同负载量的样品进行了表征。结果表明,这些MgO微晶高度分散,尺寸规整,在4至10.8nm范围内。样品的比表面积、孔容和孔径随负载量的增加而减小。结果表明,表面负载高度分散MgO的γ-Al₂O₃是一种高效杀菌剂,负载量为20%的MgO的γ-Al₂O₃能杀灭99%以上的细菌和芽孢细胞。