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γ-Al2O3负载MgO纳米颗粒的制备及其杀菌性能

Preparation and bactericidal property of MgO nanoparticles on gamma-Al2O3.

作者信息

Lin Yan-Jun, Li Dian-Qing, Wang Ge, Huang Lei, Duan Xue

机构信息

Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry of Education, Beijing University of Chemical Technology, Beijing, 100029, People's Republic of China.

出版信息

J Mater Sci Mater Med. 2005 Jan;16(1):53-6. doi: 10.1007/s10856-005-6446-0.

Abstract

After being impregnated in the solution containing Mg(NO3)2 x 6H2O, gamma-Al2O3 was dried and calcined at 500 degrees C which results in the production of a bactericide, highly dispersed MgO loaded on the surface of gamma-Al2O3. The threshold value of the monolayer dispersion of MgO on gamma-Al2O3 is 14.97%, and MgO crystal formed when the load amount beyond this value. The samples with different load amount were characterized by X-ray Diffraction (XRD), Low-temperature N2 adsorption-desorption, Inductively Coupled Plasma (ICP) and High Resolution Scan Electronic Microscope (SEM). The results showed that these MgO microcrystals are highly dispersed and have regular size in the range of 4 to 10.8 nm. The specific surface, pore volume and pore size of the sample decreases with the increase of load amount. It is demonstrated that gamma-Al2O3 with highly dispersed MgO on the surface is efficient bactericide, and the one with 20% load amount of MgO can kill more than 99% bacteria and spore cells.

摘要

将γ-Al₂O₃浸渍在含有Mg(NO₃)₂·6H₂O的溶液中后,进行干燥并在500℃下煅烧,从而制得一种杀菌剂,即高度分散在γ-Al₂O₃表面的MgO。MgO在γ-Al₂O₃上的单层分散阈值为14.97%,当负载量超过此值时会形成MgO晶体。采用X射线衍射(XRD)、低温N₂吸附-脱附、电感耦合等离子体(ICP)和高分辨率扫描电子显微镜(SEM)对不同负载量的样品进行了表征。结果表明,这些MgO微晶高度分散,尺寸规整,在4至10.8nm范围内。样品的比表面积、孔容和孔径随负载量的增加而减小。结果表明,表面负载高度分散MgO的γ-Al₂O₃是一种高效杀菌剂,负载量为20%的MgO的γ-Al₂O₃能杀灭99%以上的细菌和芽孢细胞。

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