通过调节离子转移通量对液-液界面处表面受限反应进行可逆电化学监测。
Reversible electrochemical monitoring of surface confined reactions at liquid-liquid interfaces by modulation of ion transfer fluxes.
作者信息
Xu Yida, De Marco Roland, Shvarev Alexey, Bakker Eric
机构信息
Department of Chemistry and Biochemistry, Auburn University, Auburn, AL 36849, USA.
出版信息
Chem Commun (Camb). 2005 Jun 28(24):3074-6. doi: 10.1039/b503548a. Epub 2005 May 11.
DOI:10.1039/b503548a
PMID:15959589
Abstract
The adsorption of the neutral surfactant Brij35 at a liquid-liquid interface is reversibly monitored via its disturbance of an electrochemically imposed ion flux across the interface, forming a promising experimental tool for the detection of surface confined reactions at such liquids and polymers.
摘要
通过监测中性表面活性剂Brij35对跨界面电化学施加离子通量的干扰，可逆地监测其在液 - 液界面的吸附情况，这为检测此类液体和聚合物表面受限反应形成了一种很有前景的实验工具。
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