基于自组装的苝二酰亚胺连接六氮杂三亚苯的光捕获与能量转移系统。

Light-harvesting and energy-transfer system based on self-assembling perylene diimide-appended hexaazatriphenylene.

作者信息

Ishi-i Tsutomu, Murakami Koh-ichi, Imai Yusuke, Mataka Shuntaro

机构信息

Institute for Materials Chemistry and Engineering (IMCE) and Interdisciplinary Graduate School of Engineering Sciences, Kyushu University, Kasuga, Japan.

出版信息

Org Lett. 2005 Jul 21;7(15):3175-8. doi: 10.1021/ol050919t.

DOI:10.1021/ol050919t

PMID:16018614

Abstract

[reaction: see text]. Six perylene diimide-appended hexaazatriphenylene, HAT-PDI(6), was self-assembled in both solution and film state to form a highly stabilized dimer aggregate, in which an efficient energy transfer occurs from the hexaazatriphenylene core to the perylene-diimide moiety.

摘要

[反应：见正文]。六种并连苝二亚胺的六氮杂三亚苯，即HAT-PDI(6)，在溶液和薄膜状态下均能自组装形成高度稳定的二聚体聚集体，其中六氮杂三亚苯核心到苝二亚胺部分发生了高效的能量转移。