具有手性银螺旋配合物的对映体互穿三维网络。
Enantiomeric interpenetrating 3D nets with chiral silver helicates.
作者信息
Bai Yan, Duan Chun-Ying, Cai Ping, Dang Dong-Bin, Meng Qing-Jin
机构信息
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China.
出版信息
Dalton Trans. 2005 Aug 21(16):2678-80. doi: 10.1039/b506596h. Epub 2005 Jul 18.
DOI:10.1039/b506596h
PMID:16075105
Abstract
A new enantiomeric interpenetrating 3D nets with chiral helical coordination silver(i) polymer was achieved via self-assembly using the new ligand modular approach, in which the special helical conformation of the ligand provided the opportunity to translate chirality from one metal center to others.
摘要
通过使用新的配体模块化方法进行自组装，得到了一种具有手性螺旋配位银（I）聚合物的新型对映体互穿三维网络，其中配体的特殊螺旋构象为将手性从一个金属中心传递到其他金属中心提供了机会。
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