使用S-苯基七碳糖苷供体合成α-D-艾杜糖七碳糖苷。
Synthesis of alpha-D-idoseptanosyl glycosides using an S-phenyl septanoside donor.
作者信息
Castro Steve, Fyvie W Sean, Hatcher Susan A, Peczuh Mark W
机构信息
Department of Chemistry, University of Connecticut, 55 North Eagleville Road U-3060, Storrs, Connecticut 06269, USA.
出版信息
Org Lett. 2005 Oct 13;7(21):4709-12. doi: 10.1021/ol051912e.
PMID:16209516
Abstract
[reaction: see text] An S-phenyl alpha-D-idoseptanoside donor was used in the selective preparation of a series of alpha-D-idoseptanosyl glycosides. Glycosylation of a methyl beta-D-glycero-D-guloseptanoside acceptor with the new donor constituted the first synthesis of a septanose disaccharide.
摘要
[反应：见正文] 一种S-苯基α-D-艾杜庚糖苷供体被用于一系列α-D-艾杜庚糖基糖苷的选择性制备。用新的供体对甲基β-D-甘油-D-古洛庚糖苷受体进行糖基化反应构成了庚糖二糖的首次合成。
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