Enantioselective conjugate addition of phenylboronic acid to enones catalysed by a chiral tropos/atropos rhodium complex at the coalescence temperature.
作者信息
Monti Chiara, Gennari Cesare, Piarulli Umberto
机构信息
Dipartimento di Chimica Organica e Industriale, Centro di Eccellenza C. I. S. I., Università degli Studi di Milano, Istituto di Scienze e Tecnologie Molecolari (ISTM) del CNR, Via G. Venezian 21, Milan 20133, Italy.
出版信息
Chem Commun (Camb). 2005 Nov 14(42):5281-3. doi: 10.1039/b508832a. Epub 2005 Sep 21.
DOI:10.1039/b508832a
PMID:16244728
Abstract
A highly enantioselective rhodium-catalysed conjugate addition of phenylboronic acid to cyclic enones has been achieved using a dynamic library of chiral phosphorus ligands; the tropos/atropos nature of the ligands in the rhodium complex has been characterised via 31P-NMR.
摘要
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