Dupont L, Accorsi A
Institut National de l'Environnement Industriel et des Risques, Parc Technologique Alata, BP2, Verneuil-en-Halatte, France.
J Hazard Mater. 2006 Aug 25;136(3):520-5. doi: 10.1016/j.jhazmat.2005.11.105. Epub 2006 Feb 8.
Biogas is considered as a valuable source of renewable energy. Indeed, it can be turned into useful energy (heat, electricity, fuel) and can contribute to reduce greenhouse gas emissions. Knowledge of its safety characteristics is a very important practical issue. Experimental investigation of synthesised biogas explosion characteristics was conducted in a 20-L sphere at various temperatures (30-70 degrees C) and at atmospheric pressure. The studied biogas was made of 50% methane (CH(4)) and 50% carbon dioxide (CO(2)). It was also saturated with humidity: this composition is frequently met in digesters during waste methanisation. There are two inert gases in biogas: water vapour and carbon dioxide. Its vapour water content rises along with temperature. The presence of these inert gases modifies considerably biogas characteristics compared to the ones of pure methane: explosion limits are lowered and beyond 70 degrees C, water vapour content is sufficient to inert the mixture. Furthermore, explosion violence (estimated with the maximum rate of pressure rise values, (dp/dt)(max)) is three times lower for biogas than for pure methane at ambient temperature.
沼气被视为一种宝贵的可再生能源。的确,它可以转化为有用的能源(热能、电能、燃料),并有助于减少温室气体排放。了解其安全特性是一个非常重要的实际问题。在一个20升的球体中,于不同温度(30至70摄氏度)和大气压下对合成沼气的爆炸特性进行了实验研究。所研究的沼气由50%的甲烷(CH₄)和50%的二氧化碳(CO₂)组成。它还含有饱和湿度:这种成分在废物甲烷化过程中的消化池中经常出现。沼气中有两种惰性气体:水蒸气和二氧化碳。其水蒸气含量随温度升高而增加。与纯甲烷相比,这些惰性气体的存在极大地改变了沼气的特性:爆炸极限降低,并且在70摄氏度以上,水蒸气含量足以使混合物惰性化。此外,在环境温度下,沼气的爆炸强度(用最大压力上升速率值(dp/dt)max估算)比纯甲烷低三倍。