负载离子液体相（SILP）催化在连续甲醇羰基化中的首次应用。
First application of supported ionic liquid phase (SILP) catalysis for continuous methanol carbonylation.
作者信息
Riisager Anders, Jørgensen Betina, Wasserscheid Peter, Fehrmann Rasmus
机构信息
Department of Chemistry and Center for Sustainable and Green Chemistry, Technical University of Denmark, DK-2800 Kgs. Lyngby, Denmark.
出版信息
Chem Commun (Camb). 2006 Mar 7(9):994-6. doi: 10.1039/b516314e. Epub 2006 Jan 20.
DOI:10.1039/b516314e
PMID:16491187
Abstract
A solid, silica-supported ionic liquid phase (SILP) rhodium iodide Monsanto-type catalyst system, [BMIM][Rh(CO)2I2]-[BMIM]I-SiO2, exhibits excellent activity and selectivity towards acetyl products in fixed-bed, continuous gas-phase methanol carbonylation.
摘要
一种固体、二氧化硅负载的离子液体相（SILP）碘化铑孟山都型催化剂体系，[BMIM][Rh(CO)₂I₂]-[BMIM]I-SiO₂，在固定床连续气相甲醇羰基化反应中对乙酰产物表现出优异的活性和选择性。
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