Choi Myong Yong, Miller Roger E
Department of Chemistry, The University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, USA.
J Phys Chem A. 2006 Aug 3;110(30):9344-51. doi: 10.1021/jp0624146.
Infrared laser spectroscopy has been used to characterize imidazole (IM), imidazole dimer (IMD), and imidazole-water (IMW) binary systems formed in helium nanodroplets. The experimental results are compared with ab initio calculations reported here. Vibrational transition moment angles provide conclusive assignments for the various complexes studied here, including IM, one isomer of IMD, and two isomers of the IMW binary complexes.
红外激光光谱已被用于表征在氦纳米液滴中形成的咪唑（IM）、咪唑二聚体（IMD）和咪唑 - 水（IMW）二元体系。将实验结果与本文报道的从头算计算进行了比较。振动跃迁矩角为本文研究的各种配合物提供了确凿的归属，包括IM、IMD的一种异构体以及IMW二元配合物的两种异构体。
