Jagtap Sunil B, Tsogoeva Svetlana B
Institut für Organische und Biomolekulare Chemie der Georg-August-Universität Göttingen, Tammannstrasse 2, 37077, Göttingen, Germany.
Chem Commun (Camb). 2006 Dec 7(45):4747-9. doi: 10.1039/b611823b. Epub 2006 Sep 26.
A new organocatalytic system, novel chiral bisformamide and in situ generated L-proline-derived allylsilane reagent , which converts different aldimines to homoallylic amines in good to high yields (up to 95%) and good enantioselectivities (up to 85% ee) has been described.
已报道了一种新的有机催化体系、新型手性双甲酰胺和原位生成的L-脯氨酸衍生的烯丙基硅烷试剂，该体系能以良好到高的产率（高达95%）和良好的对映选择性（高达85% ee）将不同的醛亚胺转化为高烯丙基胺。
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