一种具有新型EO/EO/EO/EE配位模式的不寻常的一维叠氮锰配合物：合成、结构及磁性
An unusual 1D manganese azido complex with novel EO/EO/EO/EE coordination mode: synthesis, structure, and magnetic properties.
作者信息
Liu Fu-Chen, Zeng Yong-Fei, Zhao Jiong-Peng, Hu Bo-Wen, Bu Xian-He, Ribas Joan, Cano Joan
机构信息
Department of Chemistry, Nankai University, Tianjin 300071, China.
出版信息
Inorg Chem. 2007 Mar 5;46(5):1520-2. doi: 10.1021/ic061892s. Epub 2007 Feb 1.
PMID:17266301
Abstract
A novel one-dimensional manganese(II) azido complex, [Mn2(N3)4(phen)2]n (1), in which the azido bridging ligands take on an unusual new type of combination with the metal center as the sign of [-EO-EO-EO-EE-]n, has been hydrothermally synthesized, and its magnetic properties have been studied.
摘要
通过水热法合成了一种新型的一维叠氮锰（II）配合物[Mn2(N3)4(phen)2]n (1)，其中叠氮桥连配体与金属中心呈现出一种不寻常的新型组合，其特征为[-EO-EO-EO-EE-]n，并对其磁性能进行了研究。
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