Metal-free catalysis of sustainable Friedel-Crafts reactions: direct activation of benzene by carbon nitrides to avoid the use of metal chlorides and halogenated compounds.
作者信息
Goettmann Frederic, Fischer Anna, Antonietti Markus, Thomas Arne
机构信息
Max-Planck-Institute of Colloids and Interfaces, Department of Colloid Chemistry, Research Campus Golm, D-14424, Potsdam, Germany.
出版信息
Chem Commun (Camb). 2006 Nov 21(43):4530-2. doi: 10.1039/b608532f.
DOI:10.1039/b608532f
PMID:17283808
Abstract
The use of mesoporous graphitic C3N4 for the activation of benzene permitted to perform more sustainable Friedel-Crafts reactions by allowing to directly use carboxylic acids, alcohols and even quaternary ammoniums or urea as electrophiles.
摘要
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