Tang Kuan-Zhen, Li Ya-Fei, Tang Yu, Liu Wei-Sheng, Tang Ning, Tan Min-Yu
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, PR China.
Spectrochim Acta A Mol Biomol Spectrosc. 2007 Jul;67(3-4):858-63. doi: 10.1016/j.saa.2006.08.044. Epub 2006 Sep 5.
Solid complexes of lanthanide isothiocyanates with an amide-type tripodal ligand, 2,2',2''-nitrilotris-(N-phenylmethyl)-acetamide (L) have been synthesized and characterized by elemental analysis, infrared spectra and molar conductivity measurements. At the same time, the luminescent properties of the Sm(III), Eu(III), Tb(III), Dy(III) isothiocyanate complexes in solid state and the Tb(III) complex in solvents were also investigated.
合成了镧系异硫氰酸盐与酰胺型三脚架配体2,2',2''-次氮基三-(N-苯基甲基)-乙酰胺（L）的固体配合物，并通过元素分析、红外光谱和摩尔电导率测量对其进行了表征。同时，还研究了固态下Sm(III)、Eu(III)、Tb(III)、Dy(III)异硫氰酸盐配合物以及溶剂中Tb(III)配合物的发光性质。
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