一种模仿紫色酸性磷酸酶结构和功能特性的前所未有的Fe(III)(μ-OH)Zn(II)配合物。 - Suppr

An unprecedented Fe(III)(mu-OH)Zn(II) complex that mimics the structural and functional properties of purple acid phosphatases.

作者信息

Neves Ademir, Lanznaster Mauricio, Bortoluzzi Adailton J, Peralta Rosely A, Casellato Annelise, Castellano Eduardo Ernesto, Herrald Paul, Riley Mark J, Schenk Gerhard

机构信息

LABINC, Departamento de Química, Universidade Federal de Santa Catarina, 88040-900 Florianópolis, SC, Brazil.

出版信息

J Am Chem Soc. 2007 Jun 20;129(24):7486-7. doi: 10.1021/ja071184l. Epub 2007 May 23.

DOI:10.1021/ja071184l

PMID:17518469

Abstract

摘要

相似文献

An unprecedented Fe(III)(mu-OH)Zn(II) complex that mimics the structural and functional properties of purple acid phosphatases.一种模仿紫色酸性磷酸酶结构和功能特性的前所未有的Fe(III)(μ-OH)Zn(II)配合物。

J Am Chem Soc. 2007 Jun 20;129(24):7486-7. doi: 10.1021/ja071184l. Epub 2007 May 23.

Electronic structure and spectro-structural correlations of Fe(III)Zn(II) biomimetics for purple acid phosphatases: relevance to DNA cleavage and cytotoxic activity.Fe(III)Zn(II) 生物模拟物的电子结构与光谱结构相关性研究：与 DNA 切割和细胞毒性活性的相关性。

Inorg Chem. 2010 Dec 20;49(24):11421-38. doi: 10.1021/ic101433t. Epub 2010 Nov 16.

Unsymmetrical Fe(III)Co(II) and Ga(III)Co(II) complexes as chemical hydrolases: biomimetic models for purple acid phosphatases (PAPs).不对称铁（III）钴（II）和镓（III）钴（II）配合物作为化学水解酶：紫色酸性磷酸酶（PAPs）的仿生模型。

Inorg Chem. 2009 Aug 17;48(16):7905-21. doi: 10.1021/ic900831q.

Rosmarinic acid determination using biomimetic sensor based on purple acid phosphatase mimetic.基于紫色酸性磷酸酶模拟物的仿生传感器测定迷迭香酸

Anal Chim Acta. 2008 Apr 14;613(1):91-7. doi: 10.1016/j.aca.2008.02.050. Epub 2008 Feb 29.

Synthesis and characterization of the tetranuclear iron(III) complex of a new asymmetric multidentate ligand. A structural model for purple acid phosphatases.一种新型不对称多齿配体的四核铁（III）配合物的合成与表征。紫色酸性磷酸酶的结构模型。

Dalton Trans. 2007 Nov 28(44):5132-9. doi: 10.1039/b709293h. Epub 2007 Sep 6.

Evidence for nonbridged coordination of p-nitrophenyl phosphate to the dinuclear Fe(III)-M(II) center in bovine spleen purple acid phosphatase during enzymatic turnover.在酶促周转过程中，对硝基苯磷酸与牛脾紫色酸性磷酸酶中双核Fe(III)-M(II)中心非桥连配位的证据。

Biochemistry. 1999 Aug 3;38(31):9914-25. doi: 10.1021/bi9904454.

Spectroscopic and catalytic characterization of a functional Fe(III)Fe(II) biomimetic for the active site of uteroferrin and protein cleavage.光谱和催化特性的功能性 Fe(III)Fe(II)仿生模拟物的尿铁蛋白活性位点和蛋白裂解。

Inorg Chem. 2012 Feb 20;51(4):2065-78. doi: 10.1021/ic201711p. Epub 2012 Jan 30.

Monoesterase activity of a purple acid phosphatase mimic with a cyclam platform.具有环瓜平台的紫色酸性磷酸酶模拟物的单酯酶活性。

Chemistry. 2012 Feb 6;18(6):1700-10. doi: 10.1002/chem.201100229. Epub 2012 Jan 10.

Crystal structure of a purple acid phosphatase containing a dinuclear Fe(III)-Zn(II) active site.含有双核Fe(III)-Zn(II)活性位点的紫色酸性磷酸酶的晶体结构。

Science. 1995 Jun 9;268(5216):1489-92. doi: 10.1126/science.7770774.

The Fe(III)Zn(II) form of recombinant human purple acid phosphatase is not activated by proteolysis.

J Inorg Biochem. 2005 Feb;99(2):521-9. doi: 10.1016/j.jinorgbio.2004.10.029.

引用本文的文献

A novel simplified structural design as an artificial enzyme for efficient hydrolysis of PNPA.一种用于高效水解对硝基苯磷酸酯的新型简化结构人工酶设计。

Sci Rep. 2025 Mar 17;15(1):9071. doi: 10.1038/s41598-025-92439-1.

Phosphoester bond hydrolysis by a discrete zirconium-oxo cluster: mechanistic insights into the central role of the binuclear Zr-Zr active site.离散的锆氧簇对磷酸酯键的水解作用：对双核Zr-Zr活性位点核心作用的机理洞察

Chem Sci. 2024 Oct 2;15(43):18008-21. doi: 10.1039/d4sc03946g.

Fe-Ni porphyrin/mesoporous titania thin film electrodes: a bioinspired nanoarchitecture for photoelectrocatalysis.铁镍卟啉/介孔二氧化钛薄膜电极：一种用于光电催化的受生物启发的纳米结构。

RSC Adv. 2024 May 15;14(23):15832-15839. doi: 10.1039/d3ra08047a.

Ce-based solid-phase catalysts for phosphate hydrolysis as new tools for next-generation nanoarchitectonics.用于磷酸盐水解的铈基固相催化剂作为下一代纳米结构的新工具。

Sci Technol Adv Mater. 2023 Sep 8;24(1):2250705. doi: 10.1080/14686996.2023.2250705. eCollection 2023.

Unraveling mechanisms of the uncoordinated nucleophiles: theoretical elucidations of the cleavage of bis(-nitrophenyl) phosphate mediated by zinc-complexes with apical nucleophiles.解析非协同亲核试剂的作用机制：锌配合物与顶端亲核试剂介导的双（对硝基苯基）磷酸酯裂解的理论阐释

RSC Adv. 2019 Nov 19;9(65):37696-37704. doi: 10.1039/c9ra06737j.

Mono- and dinuclear zinc complexes bearing identical bis(thiosemicarbazone) ligand that exhibit alkaline phosphatase-like catalytic reactivity.单核和双核锌配合物，均含有相同的双（硫代缩氨基甲酸盐）配体，表现出碱性磷酸酶样的催化反应活性。

J Biol Inorg Chem. 2022 Feb;27(1):37-47. doi: 10.1007/s00775-021-01909-0. Epub 2021 Oct 29.

Tuning metal-metal interactions for cooperative small molecule activation.调控金属-金属相互作用以实现协同小分子活化。

Chem Commun (Camb). 2021 Mar 21;57(23):2839-2853. doi: 10.1039/d0cc07721f. Epub 2021 Feb 24.

Modeling the Active Site of the Purple Acid Phosphatase Enzyme with Hetero-Dinuclear Mixed Valence M(II)-Fe(III) [M = Zn, Ni, Co, and Cu] Complexes Supported over a [NO] Unsymmetrical Ligand.用负载于[NO]不对称配体上的异双核混合价态M(II)-Fe(III) [M = Zn、Ni、Co和Cu]配合物对紫色酸性磷酸酶的活性位点进行建模。

ACS Omega. 2017 Aug 21;2(8):4737-4750. doi: 10.1021/acsomega.7b00671. eCollection 2017 Aug 31.

Guanidine- and purine-functionalized ligands of FeZn complexes: effects on the hydrolysis of DNA.胍基和嘌呤基功能化的 FeZn 配合物配体：对 DNA 水解的影响。

J Biol Inorg Chem. 2019 Aug;24(5):675-691. doi: 10.1007/s00775-019-01680-3. Epub 2019 Jul 2.

Analysis of the Puzzling Exchange-Coupling Constants in a Series of Heterobimetallic Complexes.一系列异双金属配合物中令人费解的交换耦合常数分析

Inorg Chem. 2019 Jul 15;58(14):9150-9160. doi: 10.1021/acs.inorgchem.9b00757. Epub 2019 Jun 26.

文献AI研究员

20分钟写一篇综述，助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型，支持多种主流文档格式。

立即体验

An unprecedented Fe(III)(mu-OH)Zn(II) complex that mimics the structural and functional properties of purple acid phosphatases.

作者信息

机构信息

出版信息

相似文献

引用本文的文献

文献AI研究员

用中文搜PubMed

文档翻译

Suppr 超能文献

相似文献

引用本文的文献