Xu G R, Zou J L, Li G B
School of Municipal and Environmental Engineering, Harbin Institute of Technology, P.O. Box 2602, Harbin, Heilongjiang Province, China.
J Hazard Mater. 2008 Jan 31;150(2):394-400. doi: 10.1016/j.jhazmat.2007.04.121. Epub 2007 May 3.
In order to investigate the effect of sintering temperature on the characteristics of sludge ceramsite and find an optimal sintering temperature, dried sewage sludge, clay, and water glass were mixed at ratios of dried sewage sludge/clay=33% and water glass/clay=15%. Then these mixtures were heated to 850, 900, 950, 1000, 1100, and 1200 degrees C for production of sludge ceramsite. The sludge ceramsite were characterized by DTA-TGA, SEM-EDS, XRD, and XRF. The results indicate that the differences in thermal behaviours are caused by the compositional and structural variations; the ceramsite sintered at 1000 degrees C has more uniformly distributed finer pores (0.5 microm<pore size<10.0 microm), while the ceramsite sintered at other temperatures has less pores and rougher surfaces. The main crystalline phases of ceramsite are quartz and kyanite below 1000 degrees C; kyanite is the main crystalline phase at 1000 and 1100 degrees C, and most of the crystalline phases are mullite at 1200 degrees C. It is therefore concluded that sintering temperature has a significant effect on the characteristics of sludge ceramsite, and that 1000 degrees C is the optimal sintering temperature.
为了研究烧结温度对污泥陶粒特性的影响并找到最佳烧结温度,将干化的污水污泥、黏土和水玻璃按干化污水污泥/黏土 = 33%以及水玻璃/黏土 = 15%的比例混合。然后将这些混合物加热至850、900、950、1000、1100和1200摄氏度以生产污泥陶粒。采用差示扫描量热-热重联用仪(DTA-TGA)、扫描电子显微镜-能谱仪(SEM-EDS)、X射线衍射仪(XRD)和X射线荧光光谱仪(XRF)对污泥陶粒进行表征。结果表明,热行为的差异是由成分和结构变化引起的;在1000摄氏度烧结的陶粒具有分布更均匀的细孔(0.5微米<孔径<10.0微米),而在其他温度烧结的陶粒孔隙较少且表面更粗糙。低于1000摄氏度时陶粒的主要晶相为石英和蓝晶石;在1000和1100摄氏度时蓝晶石是主要晶相,在1200摄氏度时大部分晶相为莫来石。因此得出结论,烧结温度对污泥陶粒的特性有显著影响,1000摄氏度是最佳烧结温度。