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Corridor of existence of thermodynamically consistent solution of the Ornstein-Zernike equation.

作者信息

Vorob'ev V S, Martynov G A

机构信息

Joint Institute for High Temperatures of RAS, Moscow, Russia.

出版信息

J Chem Phys. 2007 Jul 14;127(2):024508. doi: 10.1063/1.2749253.

Abstract

We obtain the exact equation for a correction to the Ornstein-Zernike (OZ) equation based on the assumption of the uniqueness of thermodynamical functions. We show that this equation is reduced to a differential equation with one arbitrary parameter for the hard sphere model. The compressibility factor within narrow limits of this parameter variation can either coincide with one of the formulas obtained on the basis of analytical solutions of the OZ equation or assume all intermediate values lying in a corridor between these solutions. In particular, we find the value of this parameter when the thermodynamically consistent compressibility factor corresponds to the Carnahan-Stirling formula.

摘要

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