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基于电热变压吸附的活性炭对有机蒸汽的稳态和动态解吸

Steady-state and dynamic desorption of organic vapor from activated carbon with electrothermal swing adsorption.

作者信息

Emamipour Hamidreza, Hashisho Zaher, Cevallos Diego, Rood Mark J, Thurston Deborah L, Hay K James, Kim Byung J, Sullivan Patrick D

机构信息

Department of Civil and Environmental Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, USA.

出版信息

Environ Sci Technol. 2007 Jul 15;41(14):5063-9. doi: 10.1021/es0703022.

Abstract

A new method to achieve steady-state and dynamic-tracking desorption of organic compounds from activated carbon was developed and tested with a bench-scale system. Activated carbon fiber cloth (ACFC) was used to adsorb methyl ethyl ketone (MEK) from air streams. Direct electrothermal heating was then used to desorb the vapor to generate select vapor concentrations at 500 ppmv and 5000 ppmv in air. Dynamic-tracking desorption was also achieved with carefully controlled yet variable vapor concentrations between 250 ppmv and 5000 ppmv, while also allowing the flow rate of the carrier gas to change by 100%. These results were also compared to conditions when recovering MEK as a liquid, and using microwaves as the source of energy to regenerate the adsorbent to provide MEK as a vapor or a liquid.

摘要

开发了一种实现从活性炭中稳定状态和动态跟踪解吸有机化合物的新方法,并在实验室规模系统中进行了测试。使用活性炭纤维布(ACFC)从气流中吸附甲乙酮(MEK)。然后采用直接电热加热解吸蒸汽,以在空气中产生500 ppmv和5000 ppmv的选定蒸汽浓度。还通过在250 ppmv至5000 ppmv之间仔细控制但可变的蒸汽浓度实现了动态跟踪解吸,同时还允许载气流量变化100%。还将这些结果与将MEK回收为液体以及使用微波作为能量源再生吸附剂以提供蒸汽或液体形式的MEK的条件进行了比较。

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