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单甘油酯和二甘油酯的三甲基硅烷基衍生物在具有非极性固定相的毛细管柱上的气相色谱保留指数

Gas chromatographic retention indices of trimethylsilyl derivatives of mono- and diglycerides on capillary columns with non-polar stationary phases.

作者信息

Isidorov V A, Rusak M, Szczepaniak L, Witkowski S

机构信息

Institute of Chemistry, Białystok University, 15-399 Białystok, Poland.

出版信息

J Chromatogr A. 2007 Sep 28;1166(1-2):207-11. doi: 10.1016/j.chroma.2007.07.047. Epub 2007 Jul 28.

Abstract

Mono- and diglycerides play an important role in the metabolism of plants and animals. They are usually constitutive elements of complex mixtures and are not always as main components, which considerably hinder the identification of these analytes. This work communicates about a synthesis of a wide range of esters of glycerol and aliphatic C(6)-C(20) acids and presents gas chromatographic characteristics of 32 compounds in the form of the most reproducible parameters-linear-programmed retention indices on high-performance capillary columns with non-polar stationary phases. The article also presents mass spectra for a series of those glycerides which were not characterized earlier by these parameters.

摘要

甘油单酯和甘油二酯在动植物代谢中发挥着重要作用。它们通常是复杂混合物的组成成分,并不总是作为主要成分,这在很大程度上阻碍了这些分析物的鉴定。本文报道了一系列甘油与脂肪族C(6)-C(20)酸酯的合成,并以最具重现性的参数——在具有非极性固定相的高效毛细管柱上的线性程序保留指数的形式,给出了32种化合物的气相色谱特征。本文还给出了一系列此前未用这些参数表征的甘油酯的质谱图。

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