Shenoy Vijay B, Rao C N R
Centre for Condensed Matter Theory, Department of Physics, Indian Institute of Science, Bangalore 560 012, India.
Philos Trans A Math Phys Eng Sci. 2008 Jan 13;366(1862):63-82. doi: 10.1098/rsta.2007.2140.
Transition metal oxides, such as the mixed-valent rare-earth manganites Ln(1-x)AxMnO3 (Ln, rare-earth ion, and A, alkaline-earth ion), show a variety of electronic orders with spatially correlated charge, spin and orbital arrangements, which in turn give rise to many fascinating phenomena and properties. These materials are also electronically inhomogeneous, i.e. they contain disjoint spatial regions with different electronic orders. Not only do we observe signatures of such electronic phase separation in a variety of properties, but we can also observe the different 'phases' visually through different types of imaging. We discuss various experiments pertaining to electronic orders and electronic inhomogeneities in the manganites and present a discussion of theoretical approaches to their understanding. It is noteworthy that the mixed-valent rare-earth cobaltates of the type Ln(1-x)AxCoO3 also exhibit electronic inhomogeneities just as the manganites.
过渡金属氧化物,如混合价态的稀土锰酸盐Ln(1-x)AxMnO3(Ln为稀土离子,A为碱土离子),呈现出多种具有空间相关电荷、自旋和轨道排列的电子有序态,进而产生许多引人入胜的现象和性质。这些材料在电子方面也是不均匀的,即它们包含具有不同电子有序态的不相连空间区域。我们不仅在各种性质中观察到这种电子相分离的特征,还能通过不同类型的成像在视觉上观察到不同的“相”。我们讨论了与锰酸盐中电子有序态和电子不均匀性相关的各种实验,并对理解它们的理论方法进行了讨论。值得注意的是,Ln(1-x)AxCoO3型的混合价态稀土钴酸盐也和锰酸盐一样表现出电子不均匀性。