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固体 C60 的可压缩性。

Compressibility of solid c60.

出版信息

Science. 1991 May 31;252(5010):1288-90. doi: 10.1126/science.252.5010.1288.

Abstract

Room-temperature powder x-ray diffraction profiles have been obtained at hydrostatic pressures P = 0 and 1.2 gigapascals on the solid phase of cubic C(60) ("fullerite"). Within experimental error, the linear compressibility d(ln a)/dP is the same as the interlayer compressibility d(ln c)/dP of hexagonal graphite, consistent with van der Waals intermolecular bonding. The volume compressibility -d(ln V)/dP is 7.0 +/- 1 x 10(-12) square centimeter per dyne, 3 and 40 times the values for graphite and diamond, respectively.

摘要

室温粉末 X 射线衍射图谱在静水压力 P = 0 和 12 吉帕斯卡下获得了立方 C(60)(“富勒烯”)的固相。在实验误差范围内,线性压缩率 d(ln a)/dP 与六方石墨的层间压缩率 d(ln c)/dP 相同,符合范德华分子间键合。体积压缩率-d(ln V)/dP 为 7.0 +/- 1 x 10(-12) 平方厘米每达因,分别是石墨和金刚石的 3 倍和 40 倍。

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