Li S Y, Wu G, Chen X H, Taillefer Louis
Département de physique and RQMP, Université de Sherbrooke, Sherbrooke J1K 2R1, Canada.
Phys Rev Lett. 2007 Sep 7;99(10):107001. doi: 10.1103/PhysRevLett.99.107001.
The in-plane thermal conductivity kappa of the layered superconductor CuxTiSe2 was measured down to temperatures as low as Tc/40, at x=0.06 near where the charge-density-wave order vanishes. The absence of a residual linear term at T-->0 is strong evidence for conventional s-wave superconductivity in this system. This is further supported by the slow magnetic field dependence, also consistent with a single gap, of uniform magnitude across the Fermi surface. Comparison with the closely related material NbSe2, where the superconducting gap is 3 times larger on the Nb 4d band than on the Se 4p band, suggests that in Cu0.06TiSe2 the Se 4p band is below the Fermi level and Cu doping into the Ti 3d band is responsible for the superconductivity.
在电荷密度波序消失的附近,即x = 0.06处,对层状超导体CuxTiSe2的面内热导率κ进行了测量,测量温度低至Tc/40。在T→0时没有残余线性项,这是该系统中传统s波超导性的有力证据。费米面各处均匀大小的单能隙的缓慢磁场依赖性也支持了这一点。与密切相关的材料NbSe2相比,NbSe2中Nb 4d带上的超导能隙比Se 4p带上的大3倍,这表明在Cu0.06TiSe2中,Se 4p带低于费米能级,向Ti 3d带中掺杂Cu导致了超导性。