Lutti A, Callaghan P T
MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Chemical and Physical Sciences, Victoria University of Wellington, New Zealand.
Eur Phys J E Soft Matter. 2007 Oct;24(2):129-37. doi: 10.1140/epje/i2007-10222-4. Epub 2007 Nov 6.
Lamellar systems are self-assemblies of surfactant molecules forming planar bilayers separated by layers of solvent. At sufficiently high shear rates, they are known to form spherical objects often referred to as onions. In this paper, we are concerned with the effect of shear on those multi-lamellar vesicles. We measure solvent diffusion by nuclear magnetic resonance (NMR) using a method which is sensitive to the time dependence of mean-squared displacements. This method, combined with NMR velocimetry, allows us to infer onion structure as a function of shear rate, identifying different regimes in which local viscosity is related to the onion size. The role of slip is examined and the stress dependence of wall slip velocities is determined.
层状体系是表面活性剂分子的自组装体,形成由溶剂层分隔的平面双层结构。在足够高的剪切速率下,已知它们会形成通常被称为“洋葱”的球形物体。在本文中,我们关注剪切对那些多层囊泡的影响。我们使用一种对均方位移的时间依赖性敏感的方法,通过核磁共振(NMR)测量溶剂扩散。这种方法与NMR测速法相结合,使我们能够推断出洋葱结构与剪切速率的函数关系,识别出局部粘度与洋葱大小相关的不同状态。研究了滑移的作用,并确定了壁面滑移速度的应力依赖性。