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高性能碳纳米管纤维。

High-performance carbon nanotube fiber.

作者信息

Koziol Krzysztof, Vilatela Juan, Moisala Anna, Motta Marcelo, Cunniff Philip, Sennett Michael, Windle Alan

机构信息

Department of Materials Science, University of Cambridge, Pembroke Street, Cambridge CB2 3QZ, UK.

出版信息

Science. 2007 Dec 21;318(5858):1892-5. doi: 10.1126/science.1147635. Epub 2007 Nov 15.

Abstract

With their impressive individual properties, carbon nanotubes should form high-performance fibers. We explored the roles of nanotube length and structure, fiber density, and nanotube orientation in achieving optimum mechanical properties. We found that carbon nanotube fiber, spun directly and continuously from gas phase as an aerogel, combines high strength and high stiffness (axial elastic modulus), with an energy to breakage (toughness) considerably greater than that of any commercial high-strength fiber. Different levels of carbon nanotube orientation, fiber density, and mechanical properties can be achieved by drawing the aerogel at various winding rates. The mechanical data obtained demonstrate the considerable potential of carbon nanotube assemblies in the quest for maximal mechanical performance. The statistical aspects of the mechanical data reveal the deleterious effect of defects and indicate strategies for future work.

摘要

凭借其令人印象深刻的独特性能,碳纳米管理应能形成高性能纤维。我们探究了纳米管长度与结构、纤维密度以及纳米管取向在实现最佳机械性能方面所起的作用。我们发现,以气凝胶形式直接从气相连续纺丝而成的碳纳米管纤维,兼具高强度和高刚度(轴向弹性模量),其断裂能量(韧性)比任何商用高强度纤维都要大得多。通过以不同的缠绕速率拉伸气凝胶,可实现不同程度的碳纳米管取向、纤维密度和机械性能。所获得的力学数据表明,碳纳米管组件在追求最大机械性能方面具有巨大潜力。力学数据的统计分析揭示了缺陷的有害影响,并指明了未来工作的策略。

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