从半日花烷型二萜到菖蒲烷型二萜。二氢扎莫烷酸侧链的降解。
From labdanes to drimanes. Degradation of the side chain of dihydrozamoranic acid.
作者信息
Rodilla Jesús M L, Díez D, Urones J G, Rocha Pedro M
机构信息
Departamento de Química, Universidade da Beira Interior, 6201-001 Covilhã, Portugal.
出版信息
Molecules. 2004 Apr 30;9(5):300-22. doi: 10.3390/90500300.
Abstract
A new route for the degradation of the saturated side chain of dihydrozamoranic acid has been devised, giving an advanced intermediate, compound 14, useful for the synthesis of insect antifeedants such as warburganal and polygodial.
摘要
已设计出一种新的途径用于降解二氢扎莫拉酸的饱和侧链，得到一种高级中间体化合物14，其可用于合成昆虫拒食剂，如沃伯格醛和多戈醛。
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