膦腈在均相催化中作为配体的研究进展、概念及展望
Phosphinines as ligands in homogeneous catalysis: recent developments, concepts and perspectives.
作者信息
Müller Christian, Vogt Dieter
机构信息
Schuit Institute for Catalysis, Laboratory of Homogeneous Catalysis, Eindhoven University of Technology, Den Dolech 2, 5600, MB, Eindhoven, The Netherlands.
出版信息
Dalton Trans. 2007 Dec 21(47):5505-23. doi: 10.1039/b712456m. Epub 2007 Sep 12.
DOI:10.1039/b712456m
PMID:18043811
Abstract
Phosphinines belong to an intriguing class of phosphorus-containing heterocycles with interesting steric, electronic and coordinating properties. This article focuses on recent developments, concepts and perspectives in the field of phosphinines and phosphinine-based ligands and their application as ligands in homogeneous catalytic reactions.
摘要
磷杂苯属于一类有趣的含磷杂环化合物，具有引人关注的空间、电子和配位性质。本文重点介绍磷杂苯及其基配体领域的最新进展、概念和前景，以及它们在均相催化反应中作为配体的应用。
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