聚硅烷负载钯/氧化铝杂化催化剂的研制及其在氢化反应中的应用。
Development of polysilane-supported palladium/alumina hybrid catalysts and their application to hydrogenation.
作者信息
Oyamada Hidekazu, Naito Takeshi, Miyamoto Shinpei, Akiyama Ryo, Hagio Hiroyuki, Kobayashi Shū
机构信息
Department of Chemistry, School of Science and Graduate School of Pharmaceutical Sciences, The University of Tokyo, The HFRE Division, ERATO, Japan Science and Technology Agency (JST), Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan.
出版信息
Org Biomol Chem. 2008 Jan 7;6(1):61-5. doi: 10.1039/b715220e. Epub 2007 Nov 23.
DOI:10.1039/b715220e
PMID:18075649
Abstract
Novel immobilized Pd catalysts, polysilane-supported palladium/alumina hybrid catalysts, have been developed. The catalysts showed high catalytic activity for hydrogenation, and could be used in an organic solvent or under solvent-free conditions.
摘要
新型固定化钯催化剂，即聚硅烷负载的钯/氧化铝混合催化剂已被开发出来。这些催化剂对氢化反应表现出高催化活性，并且可在有机溶剂中或无溶剂条件下使用。
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