钯（0）催化的2'-炔基丁酸-2,3-二烯酯脱羧反应：2-炔基丁-1,3-二烯的合成方法
Palladium(0)-catalyzed decarboxylation of buta-2,3-dienyl 2'-alkynoates: approach to the synthesis of 2-alkynyl buta-1,3-dienes.
作者信息
Sim So Hee, Park Hee-Jun, Lee Sang Ick, Chung Young Keun
机构信息
Intelligent Textile System Research Center, and Department of Chemistry, College of Natural Sciences, Seoul National University, Seoul 151-747, Korea.
出版信息
Org Lett. 2008 Feb 7;10(3):433-6. doi: 10.1021/ol702577g. Epub 2008 Jan 3.
PMID:18171070
Abstract
The Pd(PPh3)4-catalyzed decarboxylation of buta-2,3-dienyl 2'-alkynoates allows the rapid construction of 2-alkynyl buta-1,3-dienes. The carbon-carbon bond-forming reaction occurs at the central position of an allene moiety.
摘要
四（三苯基膦）钯催化的2-炔基-2,3-丁二烯酸酯的脱羧反应能够快速构建2-炔基-1,3-丁二烯。碳-碳键形成反应发生在丙二烯部分的中心位置。
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