Bailey A E, Poon W C K, Christianson R J, Schofield A B, Gasser U, Prasad V, Manley S, Segre P N, Cipelletti L, Meyer W V, Doherty M P, Sankaran S, Jankovsky A L, Shiley W L, Bowen J P, Eggers J C, Kurta C, Lorik T, Pusey P N, Weitz D A
Dept. of Physics & SEAS, Harvard University, Cambridge, Massachusetts 02138, USA.
Phys Rev Lett. 2007 Nov 16;99(20):205701. doi: 10.1103/PhysRevLett.99.205701. Epub 2007 Nov 12.
We study phase separation in a deeply quenched colloid-polymer mixture in microgravity on the International Space Station using small-angle light scattering and direct imaging. We observe a clear crossover from early-stage spinodal decomposition to late-stage, interfacial-tension-driven coarsening. Data acquired over 5 orders of magnitude in time show more than 3 orders of magnitude increase in domain size, following nearly the same evolution as that in binary liquid mixtures. The late-stage growth approaches the expected linear growth rate quite slowly.
我们利用小角光散射和直接成像技术,在国际空间站的微重力环境下研究了深度淬火的胶体-聚合物混合物中的相分离现象。我们观察到从早期的旋节线分解到后期的界面张力驱动粗化的明显转变。在5个数量级的时间内获取的数据显示,畴尺寸增加了3个多数量级,其演化过程与二元液体混合物几乎相同。后期的生长非常缓慢地接近预期的线性生长速率。