Chremos Alexandros, Camp Philip J
School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh EH9 3JJ, United Kingdom.
Phys Rev E Stat Nonlin Soft Matter Phys. 2007 Nov;76(5 Pt 2):056108. doi: 10.1103/PhysRevE.76.056108. Epub 2007 Nov 13.
The neighbor network in a two-dimensional polydisperse hard-disk fluid with diameter distribution p(sigma) approximately sigma(-4) is examined using constant-pressure Monte Carlo simulations. Graphs are constructed from vertices (disks) with edges (links) connecting each vertex to k neighboring vertices defined by a radical tessellation. At packing fractions in the range 0.24< or =eta< or =0.36, the decay of the network degree distribution is observed to be consistent with the power law k(-gamma) where the exponent lies in the range 5.6< or =gamma< or =6.0 . Comparisons with the predictions of a maximum-entropy theory suggest that this apparent power-law behavior is not the asymptotic one and that p(k) approximately k(-4) in the limit k-->infinity. This is consistent with the simple idea that for large disks, the number of neighbors is proportional to the disk diameter. A power-law decay of the network degree distribution is one of the characteristics of a scale-free network. The assortativity of the network is measured and is found to be positive, meaning that vertices of equal degree are connected more often than in a random network. Finally, the equation of state is determined and compared with the prediction from a scaled-particle theory. Very good agreement between simulation and theory is demonstrated.
使用恒压蒙特卡罗模拟研究了直径分布(p(\sigma)\approx\sigma^{-4})的二维多分散硬磁盘流体中的邻居网络。通过顶点(磁盘)构建图形,边(链接)将每个顶点连接到由径向镶嵌定义的(k)个相邻顶点。在填充率范围(0.24\leqslant\eta\leqslant0.36)内,观察到网络度分布的衰减与幂律(k^{-\gamma})一致,其中指数(\gamma)在(5.6\leqslant\gamma\leqslant6.0)范围内。与最大熵理论预测的比较表明,这种明显的幂律行为不是渐近行为,并且在(k\rightarrow\infty)的极限情况下(p(k)\approx k^{-4}))。这与一个简单的想法一致,即对于大磁盘,邻居的数量与磁盘直径成正比。网络度分布的幂律衰减是无标度网络的特征之一。测量了网络的 assortativity,发现其为正,这意味着相同度数的顶点比随机网络中更频繁地相连。最后,确定了状态方程并与标度粒子理论的预测进行了比较。模拟和理论之间显示出非常好的一致性。