二甲基锌介导、叔丁基过氧化氢促进的醛的催化对映选择性Reformatsky反应。
Me2Zn mediated, tert-butylhydroperoxide promoted, catalytic enantioselective Reformatsky reaction with aldehydes.
作者信息
Cozzi Pier Giorgio, Benfatti Fides, Capdevila Montse Guiteras, Mignogna Alessandro
机构信息
Dipartimento di Chimica G. Ciamician ALMA MATER STUDIORUM, Università di Bologna, Bologna, Italy.
出版信息
Chem Commun (Camb). 2008 Jul 28(28):3317-8. doi: 10.1039/b805197f. Epub 2008 May 27.
DOI:10.1039/b805197f
PMID:18622456
Abstract
A practical and highly enantioselective catalytic Reformatsky reaction with aldehydes using a cheap, commercially available aminoalcohol as ligand is described.
摘要
本文描述了一种实用的、高度对映选择性的催化Reformatsky反应，该反应使用廉价的市售氨基醇作为配体与醛进行反应。
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