通过保留形态碳化法由碘掺杂螺旋状聚乙炔膜制备的螺旋状碳和石墨薄膜。
Helical carbon and graphitic films prepared from iodine-doped helical polyacetylene film using morphology-retaining carbonization.
作者信息
Kyotani Mutsumasa, Matsushita Satoshi, Nagai Takuro, Matsui Yoshio, Shimomura Masaki, Kaito Akira, Akagi Kazuo
机构信息
Tsukuba Research Center for Interdisciplinary Materials Science, University of Tsukuba, Tsukuba, Japan.
出版信息
J Am Chem Soc. 2008 Aug 20;130(33):10880-1. doi: 10.1021/ja803865e. Epub 2008 Jul 26.
In this communication, we report a novel preparation of the helical carbon nanofibril-fabricated thin film from the iodine-doped filmy helical polyacetylene through a carbonization process. Carbonization of the helical polyacetylene films by way of iodine doping is found to afford carbon and graphitic films completely preserving morphologies and even helical nanofibril structures.
在本通讯中，我们报道了一种通过碳化过程从碘掺杂的薄膜螺旋状聚乙炔制备螺旋状碳纳米纤维制成的薄膜的新方法。通过碘掺杂对螺旋状聚乙炔薄膜进行碳化，发现可以得到完全保留形态甚至螺旋状纳米纤维结构的碳膜和石墨膜。
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