Synthesis of directly and doubly linked dioxoisobacteriochlorin dimers.
作者信息
Hiroto Satoru, Hisaki Ichiro, Shinokubo Hiroshi, Osuka Atsuhiro
机构信息
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan.
出版信息
J Am Chem Soc. 2008 Dec 3;130(48):16172-3. doi: 10.1021/ja807659h.
PMID:18998635
Abstract
Oxidation of 2,18-diborylporphyrin provided 2,18-dihydroxyporphyrin, which shows solvent-dependent keto-enol tautomerism and dimerization through hydrogen bonding interaction in solution. Further oxidation of 2,18-dihydroxyporphyrins afforded doubly and directly linked dioxoisobacteriochlorin face-to-face dimers.
摘要
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