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Synthesis of new halogenated pentiptycene building blocks.

作者信息

Yang Jye-Shane, Yan Jyu-Lun, Jin Ying-Xue, Sun Wei-Ting, Yang Ming-Che

机构信息

Department of Chemistry, National Taiwan University, Taipei, Taiwan, 10617.

出版信息

Org Lett. 2009 Mar 19;11(6):1429-32. doi: 10.1021/ol900127m.

Abstract

The synthesis of central-ring halogenated pentiptycene phenols 12-14 and dihalogenated pentiptycenes 15-17 is reported. Their utilities as building blocks for preparing new pentiptycene-derived pi-conjugated systems through the Sonogashira, Heck, and Suzuki reactions are also demonstrated.

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