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褐煤底灰地质聚合物砂浆的工作性和强度

Workability and strength of lignite bottom ash geopolymer mortar.

作者信息

Sathonsaowaphak Apha, Chindaprasirt Prinya, Pimraksa Kedsarin

机构信息

Department of Civil Engineering, Faculty of Engineering, Khon Kaen University, Khon Kaen, Thailand.

出版信息

J Hazard Mater. 2009 Aug 30;168(1):44-50. doi: 10.1016/j.jhazmat.2009.01.120. Epub 2009 Feb 7.

Abstract

In this paper, the waste lignite bottom ash from power station was used as a source material for making geopolymer. Sodium silicate and sodium hydroxide (NaOH) were used as liquid for the mixture and heat curing was used to activate the geopolymerization. The fineness of bottom ash, the liquid alkaline/ash ratio, the sodium silicate/NaOH ratio and the NaOH concentration were studied. The effects of the additions of water, NaOH and napthalene-based superplasticizer on the workability and strength of the geopolymer mortar were also studied. Relatively high strength geopolymer mortars of 24.0-58.0 MPa were obtained with the use of ground bottom ash with 3% retained on sieve no. 325 and mean particle size of 15.7 microm, using liquid alkaline/ash ratios of 0.429-0.709, the sodium silicate/NaOH ratios of 0.67-1.5 and 7.5-12.5M NaOH. The incorporation of water improved the workability of geopolymer mortar more effectively than the use of napthalene-based superplasticizer with similar slight reduction in strengths. The addition of NaOH solution slightly improves the workability of the mix while maintaining the strength of the geopolymer mortars.

摘要

本文以电站废弃褐煤底灰为原料制备地质聚合物。硅酸钠和氢氧化钠(NaOH)用作混合物的液体,并采用热养护来激发地质聚合反应。研究了底灰的细度、液碱/灰比、硅酸钠/NaOH比以及NaOH浓度。还研究了水、NaOH和萘系高效减水剂的添加对地质聚合物砂浆工作性能和强度的影响。使用筛孔尺寸为325号筛余3%、平均粒径为15.7微米的磨细底灰,液碱/灰比为0.429 - 0.709,硅酸钠/NaOH比为0.67 - 1.5以及NaOH浓度为7.5 - 12.5M时,可获得强度相对较高的地质聚合物砂浆,强度为24.0 - 58.0MPa。与使用萘系高效减水剂相比,加水能更有效地改善地质聚合物砂浆的工作性能,同时强度略有降低。添加NaOH溶液在保持地质聚合物砂浆强度的同时,能略微改善混合料的工作性能。

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