α-锆膦酸盐：N-杂环卡宾的通用载体。

Alpha-zirconium phosphonates: versatile supports for N-heterocyclic carbenes.

作者信息

Chessa Simona, Clayden Nigel J, Bochmann Manfred, Wright Joseph A

机构信息

Wolfson Materials and Catalysis Centre, School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich, UK NR4 7TJ.

出版信息

Chem Commun (Camb). 2009 Feb 21(7):797-9. doi: 10.1039/b821301a. Epub 2009 Jan 13.

DOI:10.1039/b821301a

PMID:19322445

Abstract

alpha-Zirconium phosphonates derivatised with N-heterocyclic carbenes provide a versatile platform for organocatalysis and metal-catalysed transformations, including the ring-opening polymerisation of cyclic esters, and olefin metathesis and hydroformylations by surface-bound ruthenium, rhodium and iridium complexes.

摘要

用N-杂环卡宾衍生化的α-锆膦酸盐为有机催化和金属催化的转化提供了一个多功能平台，包括环状酯的开环聚合，以及通过表面结合的钌、铑和铱配合物进行的烯烃复分解反应和氢甲酰化反应。