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高温气流床气化炉中的生物质-氧气气化

Biomass-oxygen gasification in a high-temperature entrained-flow gasifier.

作者信息

Zhou Jinsong, Chen Qing, Zhao Hui, Cao Xiaowei, Mei Qinfeng, Luo Zhongyang, Cen Kefa

机构信息

State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China.

出版信息

Biotechnol Adv. 2009 Sep-Oct;27(5):606-11. doi: 10.1016/j.biotechadv.2009.04.011. Epub 2009 Apr 22.

Abstract

The technology associated with indirect biomass liquefaction is currently arousing increased attention, as it could ensure a supply of transportation fuels and reduce the use of petroleum. The characteristics of biomass-oxygen gasification in a bench-scale laminar entrained-flow gasifier were studied in the paper. Experiments were carried out to investigate the influence of some key factors, including reaction temperature, residence time and oxygen/biomass ratio, on the gasification. The results indicated that higher temperature favored H2 and CO production. Cold gas efficiency was improved by N10% when the temperature was increased from 1000 to 1400 degrees C. The carbon conversion increased and the syngas quality was improved with increasing residence time. A shorter residence resulted in incomplete gasification. An optimal residence time of 1.6 s was identified in this study. The introduction of oxygen to the gasifier strengthened the gasification and improved the carbon conversion, but lowered the lower heating value and the H2/CO ratio of the syngas. The optimal oxygen/biomass ratio in this study was 0.4. The results of this study will help to improve our understanding of syngas production by biomass high-temperature gasification.

摘要

与间接生物质液化相关的技术目前正引起越来越多的关注,因为它可以确保运输燃料的供应并减少石油的使用。本文研究了在实验室规模的层流携带流气化炉中生物质-氧气气化的特性。进行了实验以研究一些关键因素,包括反应温度、停留时间和氧气/生物质比,对气化的影响。结果表明,较高的温度有利于氢气和一氧化碳的产生。当温度从1000℃升高到1400℃时,冷煤气效率提高了10%。随着停留时间的增加,碳转化率提高,合成气质量得到改善。较短的停留时间导致气化不完全。本研究确定了最佳停留时间为1.6秒。向气化炉中引入氧气增强了气化并提高了碳转化率,但降低了合成气的低位发热量和氢气/一氧化碳比。本研究中的最佳氧气/生物质比为0.4。本研究结果将有助于增进我们对生物质高温气化生产合成气的理解。

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