Zhou Jinsong, Chen Qing, Zhao Hui, Cao Xiaowei, Mei Qinfeng, Luo Zhongyang, Cen Kefa
State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China.
Biotechnol Adv. 2009 Sep-Oct;27(5):606-11. doi: 10.1016/j.biotechadv.2009.04.011. Epub 2009 Apr 22.
The technology associated with indirect biomass liquefaction is currently arousing increased attention, as it could ensure a supply of transportation fuels and reduce the use of petroleum. The characteristics of biomass-oxygen gasification in a bench-scale laminar entrained-flow gasifier were studied in the paper. Experiments were carried out to investigate the influence of some key factors, including reaction temperature, residence time and oxygen/biomass ratio, on the gasification. The results indicated that higher temperature favored H2 and CO production. Cold gas efficiency was improved by N10% when the temperature was increased from 1000 to 1400 degrees C. The carbon conversion increased and the syngas quality was improved with increasing residence time. A shorter residence resulted in incomplete gasification. An optimal residence time of 1.6 s was identified in this study. The introduction of oxygen to the gasifier strengthened the gasification and improved the carbon conversion, but lowered the lower heating value and the H2/CO ratio of the syngas. The optimal oxygen/biomass ratio in this study was 0.4. The results of this study will help to improve our understanding of syngas production by biomass high-temperature gasification.
与间接生物质液化相关的技术目前正引起越来越多的关注,因为它可以确保运输燃料的供应并减少石油的使用。本文研究了在实验室规模的层流携带流气化炉中生物质-氧气气化的特性。进行了实验以研究一些关键因素,包括反应温度、停留时间和氧气/生物质比,对气化的影响。结果表明,较高的温度有利于氢气和一氧化碳的产生。当温度从1000℃升高到1400℃时,冷煤气效率提高了10%。随着停留时间的增加,碳转化率提高,合成气质量得到改善。较短的停留时间导致气化不完全。本研究确定了最佳停留时间为1.6秒。向气化炉中引入氧气增强了气化并提高了碳转化率,但降低了合成气的低位发热量和氢气/一氧化碳比。本研究中的最佳氧气/生物质比为0.4。本研究结果将有助于增进我们对生物质高温气化生产合成气的理解。